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Cryogenic Treatment of Tubes: An Engineer’s Perspective

  1. HomeKnowledge BaseCryogenic Treatment of Tubes: An Engineer’s Perspective

Cryogenic Treatment of Tubes: An Engineer’s Perspective

by Dr Phil Taylor

As an electronics engineer, someone who works in the improbable trade of making vacuum tube “effectification” for electric guitar, I’m as motivated as anyone to find a means to improve the tone, and reliability, of these glowing, glass critters. They can be real tricky to work with. There’s variability in microphony to consider, and electrical self-noise—even between tubes from the same factory batch. I’ve often asked myself if there might be some kind of a fix for this. It seems a shame to throw a fully functional vintage tube in the trash, just because it’s subjectively a little too microphonic or noisy. I’d heard claims about how cryogenic treatment can improve the tone of tubes; claims that it, “causes metallurgical molecular changes in the metals within the tube which enhance tone and increase overall life”.

Tube on ice [photo taken by Jon Esau]

Sounds promising. But what does enhancing tone mean? Does it mean lowering noise and microphony? And can this seemingly implausible freezing process really improve a tube’s reliability and life expectancy? Could it be the silver bullet I’d been searching for? I was more than a little sceptical, but my concern with a steadily growing pile of below par tubes cluttering up my workshop drove me to explore this further—so let’s motivate! and see what cryo-treatment has to offer…

What is Cryogenic Treatment?

broken_gear_tooth
Cryogenic treatment is used to improve the durability of moving steel parts.

Cryogenic treatment is a process of cooling steel alloy down to very low temperatures (−190 °C) to increase its surface hardness to improve its resistance to wear, the practical application being to extend the life of cutting tools, gear teeth, moving engine parts, that kind of thing. These super-cooled temperatures alter the crystal structure of steel by completing the conversion of austenite to martensite making it harder. Now, I recall making a screwdriver in metalwork class at secondary school many years ago. The tip of the screwdriver was hardened by heating it up with a blowtorch and then cooling it rapidly (‘quenching’) by plunging it into a bucket of water.

It’s my understanding that quenching the steel in this way and not allowing it to cool down slowly prevents austenite from forming and makes the steel much harder and more brittle. The process isn’t 100% perfect though as steel still contains some austenite crystals. Apparently cryogenic treatment completes the conversion to further harden it.

Effect on Vacuum Tubes?

So cryogenic treatment can work to improve the hardness of ferrous metals, such as steel, but what about a vacuum tube? A tube is not a lump of steel, it’s a complex, functioning mechanism. Like an old wristwatch or a VHS video recorder, it’s composed of many different parts, with each part being made from a different type of material. In a tube the plates are typically made from aluminium coated steel, the cathode from nickel alloy, the heater wire is tungsten, the grid wire is molybdenum, the support posts are copper and the cathode is coated with a mixture of strontium/barium oxides.

Austenite and martensite crystal lattices
Two different crystal lattice structures that occur in steel which have absolutely no measurable effect on tone.

All these tiny, precision-machined metal parts are supported by thin mica discs, an arrangement often referred to as the “cage”; there’s a great deal more structure within a tube than in a lump of steel—complex, highly-organised, delicate structure. What effect does cryo-treatment have on that delicate structure of mica and metal wires suspended within its fragile glass envelope?

It’s difficult to imagine how cooling a tube down to ultracold temperatures can be of benefit to the mechanical integrity of the cage, the glass envelope or the glass-to-metal seals at the base of the tube. It could be argued, rather than improving reliability cryo-treatment does the exact opposite: the severe cooling process, if anything, degrades performance. Here’s why. Subjecting a tube to a frosty and unforgiving −190 °C will result in differential rates of thermal contraction of the various materials within the tube; no ifs, ands, or buts, its physics. As the temperature plummets, the metal pins on the base of the tube radially contract; they shrink and pull away from the surrounding glass putting stress on the “Dumet” glass-to-metal seals (US Patent 1,498,908). Technically this known as tensile stress; the forces that can arise from differential rates of thermal contraction are staggering—measured in 100,000s Kg/cm² [see the chapter on “Glass-To-Metal Sealing” in Materials and Techniques for Electron Tubes (1960) by Walter H. Kohl]. Ultimately this can lead to a breach, allowing air to enter the glass envelope and compromise the vacuum; this typically results in excessive noise, shortens tube life and can even kill the tube outright.

And the same physical principles apply to the cage. Differing rates of thermal contraction of the mica spacers and metal electrodes within the cage assembly can cause movement, potentially loosening the entire assembly resulting in adverse microphony. Given this, it should come as no surprise that:

Tube manufacturers never designed or intended tubes to be stored at cryogenic temperatures.

It’s not recommended practice to mishandle electronic components in this way. It’s worth noting that electronics component manufacturers publish datasheets that specify temperature ranges for storing and operating their devices—none recommend storing their components at temperatures colder than a midwinter’s night on Mars. In fact, thinking about it, NASA install heaters on their Mars rovers, and deep space hardware, to prevent batteries and onboard electronics being damaged by the extreme cold—NASA’s engineers are well aware of the risks involved when subjecting electronic components to extremely low temperatures.

The "cage"
How resilient is this delicate "cage" assembly of tiny metal electrodes, fine wires and brittle mica washers to ultracold temperatures?

And what goes for electronic components in general also applies to vacuum tubes. The irony of cryo-treatment is that it’s liable to ruin a tube permanently and irreversibly, rather than do anything of benefit, unless precautions are taken to protect the tube from the stresses of the procedure. The temperature must be cycled, decreased and increased, slowly for the reasons outlined above. Further, the humidity has to be maintained at near zero to prevent condensation forming and oxidising the tube pins, which are made from nickel-iron alloy. But the most worrying thing is: the tube has to be handled with the utmost care as it’s easily breakable when frozen.

At at around −200 °C many materials are fantastically fragile and prone to fracture or shattering. Metals, such as steel and aluminium, become hard and brittle and therefore prone to cracking, embrittlement and fracturing. There’s a dramatic scene in the “Terminator 2″ movie where a single bullet fired by Arnold Schwarzenegger shatters the frozen T-1000 terminator into a thousand pieces. And take a look at this short video of a platinum cup being submerged in liquid nitrogen for an experimental demonstration of how embrittlement drastically alters the properties of metals.

Other materials, surprisingly, become more ductile at low temperature, for example copper. But what about nickel, tungsten, mica, glass? How are the physical properties—ductility, malleability, stiffness, hardness, strength, size—of these diversely different materials affected? The engineers who designed tubes knew. In fact they went to great lengths to select appropriate materials and ensure the coefficients of thermal expansion for these materials were closely matched, or, if there was a mismatch, it worked in an advantageous way. They did not, however, select materials for their ability to operate at subzero temperatures. Why would they?—tubes operate at high temperature.

So cryo-treatment’s not what it’s cracked up to be. Cooling a tube down a couple hundred degrees below zero takes it far, far outside its design limits. It causes tensile and compression forces, which in turn cause movement, increasing the chances of popping a glass-to-metal seal, snapping an invisibly thin grid wire, or loosening something within the cage that was carefully and precisely aligned during the tube’s manufacture. Personally, I wouldn’t put a tube through this punishing process, for the same reason I don’t leave my vintage Fender ‘Deluxe Reverb’ amp in the boot of my car overnight, or store my ‘Strat’ in the attic—no way. And yet there are those who believe the extreme freezing process is worth the risk—to attain that ever elusive tone. So let’s push on, leave reliability behind, and explore the possible effects of cryo-treatment on audio quality.

Effect on Tone?

There is no scientific literature explaining how cryogenics improves tube tone. Not one single paper. And there are no text books or technical data published by any tube manufacturer at any time that even mentions cryogenics, let alone advocating the process as a method to alter the physical properties of a vacuum tube. So just how does it work? Does cryo-treatment affect how electrons are emitted from the cathode? Does it somehow change the way electromagnetic fields form within the tube? Does it improve the bonding of the oxide coatings to the cathode or remove residual contaminants to make the tube electrically quieter? Does cryogenic treatment affect the tube in any measurable or audible way at all? There are many questions, but no answers; how it works is… unknown. Even the handful of vendors enthusiastically pushing cryo-treatment don’t seem to know either.

Sure, they make “claims”, but claims are not a scientific explanation. Vendors discuss in great detail about how they cryogenically treat tubes, but provide no proof to support why it improves their tone. Instead their websites are littered with blurb about how their cryo-treated tubes possess “tighter focus from top to bottom”, “more holographic 3-D sound-stage”, “more subtle inner resolution extracted from recordings”, “tighter bass”, “increased dynamic range”, “faster transient response” and even references to NASA’s research and great scientists such as Albert Einstein.

G.A. Briggs A To Z In Audio
There are no audio text books that even mention cryo-treatment, let alone advocating it as procedure to improve the tone of tubes—ask G.A. Briggs.

This all sounds very impressive, but cuts no ice in science—if this extreme freezing process really does have an effect on tone then where’s the evidence? It’s not unreasonable to expect claims be supported by measurements and data; independently assessed noise and microphony tests would be a good starting point, preferably accredited by an external body such as the National Physical Laboratory. But vendors provide no hard evidence, only opinions.

Girl scientist holding test tube
“Better Tone Through Cryogenics”, eh? Has anyone put that to the test?

Given the lack of hard evidence, you could reasonably conclude that cryo-treatment’s benefits for tube tone are simply marketing hype, “snake oil“, or, at best, a placebo. But wait. Let’s just go back a step. If cryo-treatment is actually damaging tubes as speculated earlier on, then might this explain it’s apparent effectiveness? Could it be that subjecting tubes to the stresses of extreme cold provides a test methodology reveal potential early failures—a kind if negative null test? That is, the cryogenic process doesn’t improve performance, it’s simply that people are listening to hand-selected tubes; because all the infant failures, “gassy” tubes, those with poor spot welds, excessive self-noise and microphony have been weeded out. Could this be why some people can hear a difference?

So we have a “plus” for cryo-treatment, right? Well, not really. Bear in mind that the freezing process puts unnecessary stress on the glass, micas and other parts within the tube; stresses that can impair its function, cause it to fail immediately, or at some unknown point in the future. Stresses can shorten any electronic component’s life expectancy—technically, the MTBF (Mean Time Before Failure) is reduced.

By how much is impossible to say, as there are no published life test data comparing cryogenically treated and stock tubes… unsurprisingly. It would seem that all cryo-treatment is doing is introducing additional uncertainties into the manufacturing process.

The truth is out there… and a good engineer would want to know the truth—more than that, they’d need to know. It’s how they are—they have inquisitive minds. Like Einstein they’d feel compelled to understand the physics, or they’d never sleep at night. Even then, they wouldn’t get any sleep because they’d be conducting experiments late into the night; taking measurements, taking amphetamines, drinking copious amounts of strong, black coffee; they’d collect, tabulate, plot and analyse the data; they’d check and re-check experimental procedures, weigh the evidence and write up their findings. Finally, they’d submit their thesis for intense scrutiny by other boffins in the field, a ritual formally known as “peer review”. If all goes well, and they manage to survive the ravages of the peer review process, then, and only then, would it be reasonable for them to claim that “Better Tone Through Cryogenics” is fact and not just fiction. This is the way revolutionary advances in science, and guitar tone, are made. Sounds excruciatingly laborious, and it is—scientific discovery is a grindingly slow process, but it does get there in the end… eventually.

Table of results for cryo-treatment test data
Vital statistics for six JJ ECC83 tubes. One of these tubes has been cryo-treated—can you guess which one?

So, in the absence of any hard data from tube vendors I undertook my own comparative tests of cryo-treated JJ ECC83 and ECC81 tubes. They were tested against untreated reference tubes on an “AVO” MKIII Valve Characteristic Meter and later audio listening tests were performed using a Fender ‘Deluxe Reverb’ guitar amp (the tubes were substituted into the input and phase splitter stages in the amp’s circuitry). The results? Well, there were no measurable differences in self-noise (demonstrated in the short video below), gain (see the  table above) or emission. Further, “blind” A/B audio tests revealed no tonal differences or improvements between the treated and untreated tubes. The amp didn’t sound more “holographic” or “possess more subtle inner resolution”; and, unsurprisingly, it wasn’t any quieter either. This result was not unexpected.

Didn’t Mullard Know About It?

And it’s worth considering this: if there is any merit in the cryogenic treatment of tubes then surely manufacturing giants Mullard-Philips or Sylvania would have made use of the process. They were in the business of making tubes, not just for guitar and hi-fi amplifiers, but for mission critical military, aerospace and scientific instrumentation applications. They were highly motivated to improve their production processes. They had vast pool of scientific and engineering resources at their disposal. Mullard’s 43 acre site at Blackburn, Lancashire, Great Britain was one of, if not the, most advanced tube manufacturing facility in the world, and it even possessed it’s own liquid oxygen and liquid hydrogen production plant.

Mullard liquid hydrogen and oxygen tanks
Oxygen and hydrogen production plant situated within the grounds of Mullard's state-of-the-art tube manufacturing facility in Blackburn, Lancashire.

The site employed almost 7000 people amongst which were all kinds of specialists including physicists, chemists and metallurgists, resources far beyond the small handful of eastern tube factories that serve the guitar industry today. If there had been anything in cryo-treatment then surely Mullard must have known about it. Perhaps they did; perhaps somewhere, buried in some university basement, library or an old radio ham’s attic, is a technical paper written by a Mullard engineer in the early 1960s titled ‘An Investigation into the Effect of Cryogenic Temperatures on Thermionic Emission’. I’ll leave it to the reader to speculate how long the odds are of that paper ever seeing the light of day are, and, if it did ever show up, would it put the big freeze on the tube cryo-treatment industry?

How to Avoid Tube Marketing Hype 101!

Retro salesman
The power of marketing hype is the power to sell pretty much anything to anyone.

It seems to me that what little remains of the vacuum tube industry today is now suffering from a severe case of marketing hype. It’s a serious condition, and it looks terminal. Like the washing-up powder retail industry, the tube market is awash with all sorts of flimflam. And cryo-treatment is just the tip of the iceberg. There are other useless audiophile accessories, such as tube dampers, solid-state tubes, digital tube simulators/modellers, tube coolers and that old-time favorite, tube rebranding is still going strong, even today. Bizarre as it may seem, it’s still possible to purchase a newly manufactured Mullard ECC83 tube, even though Mullard ceased to exist as an entity during the last part of the 20th century.

The characters peddling such paraphernalia have no real knowledge of tubes and have nothing to offer the guitarist seeking better tone. Cheap gimmicks are no substitute for real engineering, or the real thing: the authentic tube sound. The best way to avoid being duped by marketing baloney is to educate yourself. I urge you to take a look into the pages of a few selected old tube books, such as Materials and Techniques for Electron Tubes (1960) by Walter H. Kohl the Senior Engineering Specialist of Special Tube Operations at Sylvania and Electron Tube Design by RCA (1962).

You won’t find anything about cryo-treatment within their pages, but you will uncover the priceless, hard-earned wisdom of qualified and experienced engineers. Knowledge relating to construction, materials, chemistry, metallurgy, in short, the stuff that’s relevant to making a good quality tube. Further, these books provide a fascinating, nostalgic glimpse into the world of the 1960s, a time when manufacturers went to unprecedented lengths to design and construct tubes that were as near perfect as possible. Just an evening’s reading will give you a much deeper understanding of tubes, and you’ll be on your way to becoming a bona fide tube guru.

Finally, when buying tubes, buy them from a reputable vendor, a vendor that checks them with a mutual conductance tube tester and guarantees them. Or, better still, seek out vintage vacuum tubes made by the likes of Mullard, Sylvania or the other giants from the golden age of tube manufacturing—genuine N.O.S. tubes can still be found, and, once in a while, there’s a good deal to be had.

In Conclusion

To summarise, there are variations in the construction and manufacture of vacuum tubes. This influences their tone and reliability. These variations are due to engineering limitations, or to put it another way, the manufacturers’ inability to fabricate these complex devices consistently and accurately. Mullard, and Sylvania, got as close as anyone ever could to building the perfect tube, but, despite the vast large-scale research and manufacturing facilities and wealth of expertise they had at their disposal, they were unable to attain the level of precision required to ensure their tubes possessed uniformly low microhpony and self-noise. Over the decades manufacturers made many changes to the design and construction of their tubes in an effort to iron out these problems, but they never considered deep freezing them; why would they?—there was no scientific basis to indicate it would achieve anything useful.

It would be magical if simply putting tubes in the icebox was a ‘silver bullet’ that could reduce inter-electrode movement and kill microphony; improve the insulation properties of mica spacers to prevent noisy current leakage paths; and somehow restore, revitalise and smooth out fluctuations in electron emission from the cathode oxide coating and make the tube as good as new. But I can’t begin to imagine how this “cure-all” works. “Magical” it is, because it sure isn’t science. There are no solid scientific explanations underpinning how the cryo-treatment of tubes alters their electrical and mechanical characteristics in any beneficial way. Nor are there even the most sparse comparative test results to validate claims for improved sonic performance—by the way, ‘V2’ was the cryo-treated tube in the table of tests shown earlier on.

Anyway, that’s my two cents worth. The bottom line is that cryo-treatment is no remedy for inferior materials, manufacturing defects or deterioration caused by ageing. And it won’t transform a rebranded modern manufacture ECC83 into a genuine vintage Mullard ECC83 either—it just doesn’t work that way. And, those cryo-treated tubes we tested came highly priced. Not a great financial investment—well, perhaps they were an investment; in knowledge. We’ve learned that putting a vacuum tube in the deep freeze has about as much effect on its tone as the positions of the stars and planets above—and I’ll put my money on science, rather than astrology, every time. As for my heap of dodgy old tubes, well, I’ll just have to put them back on ice…

If you’re interested in what the Mullard Blackburn factory was like in its glory days then do take a look at the following article ‘Speed, Efficiency & Perfection – Aims That Have Built a Mammoth Factory in 16 Years’ originally published in 1954 in the ‘Blackburn Times’ not long after the factory opened.

In This Section

  • Black Plate Tubes
  • Chemical Highlights of Tube Manufacturing
  • Cryogenic Treatment of Tubes: An Engineer’s Perspective
  • Developments in Trustworthy-Valve Techniques
  • Evolution of the Tube
  • Foil Those Tube Forgers
  • Microphonics
  • Mullard ECC83 (12AX7) Reissue vs Original – A Physical Comparison
  • Mullard ECC83 (12AX7) Reissue vs Original: An Electrical Comparison
  • Noise
  • Oxide Cathode Life: Investigations into the Causes of Loss of Emission
  • Secrets of the Tube Alchemists
  • Signal Tubes
  • Speed, Efficiency & Perfection – Aims That Have Built a Mammoth Factory in 16 Years
  • Subminiature Tubes: The Future of Audio!
  • That’s a Sylvania tube, the print is green, no, it’s blue
  • The ‘Magic Eye’
  • The ’12AT7′ Tube
  • The ’12AU7′ Tube
  • The ’12AX7′ Tube
  • The 12AX7 Tube: The Cornerstone of Guitar Tone
  • The 6SN7GT: The Best General-Purpose Dual Triode?
  • The Accurate BSPICE Tube Models
  • The Cool Sound of Tubes
  • The Inner Workings of Vacuum Tube Buffers
  • The Tube Family Tree – Part 1
  • The Tube Family Tree – Part 2
  • The Tube Family Tree – Part 3
  • Tube Vendors
  • Tubes: The Old Verses the New
  • Vacuum Tubes and Transistors Compared
  • Valve Microphony Part 1: Production of Microphony and Methods of Investigation
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